Web• Lithium amidotrihydroborate (LiH2NBH3 (LAB)), prepared by deprotonation (LDA) of commercial, crystalline ammonia-borane complex, provides primary alcohols: N CH3 OH … Weblactams 2, lithium amidotrihydroborate (LiNH 2 BH 3) induces the reductive opening of both the oxazolidine and lactam rings in a single synthetic step. A subsequent removal of …
Metal aminoboranes (Patent) OSTI.GOV
WebPotassium(I) amidotrihydroborate (KNH2BH3) is a newly developed potential hydrogen storage material representing a completely different structural motif within the … WebHis laboratory developed the first practical synthetic route to the tetracycline antibiotics, allowing for the synthesis of more than three thousand fully synthetic analogs … ttfwss01a
Potassium(I) amidotrihydroborate: structure and hydrogen release.
WebEvaluation of the hydrogen released, proton and boron-11 NMR spectroscopy, and infrared spectroscopy indicate the formation of a compound of composition LiAl(NHBH3)H2 in the … WebLithium amidotrihydroborate (LiH 2 NBH 3 , LAB) is a new and highly nucleophilic reducing agent that is easily prepared by deprotonation of the commercial reagent … Web17 jan. 2008 · An advanced hydrogen storage material, with potential for on‐board application, is readily prepared by mechanically milling a 1:1 ammonia borane/lithium hydride (AB/LiH) mixture. The material possesses a H capacity of around 10 wt %, higher than the 2015 DOE gravimetric H capacity target, and can rapidly release over 7 wt % … phoenix carpets stainmaster